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Share-Based Compensation (Details) (USD $)
Share data in Thousands, except Per Share data, unless otherwise specified
3 Months Ended
Mar. 31, 2012
number
Mar. 31, 2011
number
Jun. 30, 2012
Subsequent Event Restricted Stock Grant Member
Mar. 31, 2012
Stock Options
Mar. 31, 2012
Performance - Based Awards
Mar. 31, 2011
Performance - Based Awards
Mar. 31, 2012
Restricted Stock Awards
Additional Company Information [Abstract]              
Share-based compensation expense - gross $ 17,000,000 $ 14,000,000          
Share-based compensation expense net of tax 11,000,000 10,000,000          
Praxair, Inc. closing stock price 115            
Aggregate Intrinsic Value [Abstract]              
Outstanding at March 31, 2012 intrinsic value 596,000,000            
Exercisable March 31, 2012 intrinsic value 553,000,000            
Average Exercise Price [Abstract]              
Outstanding at January 1, 2012 average exercise price $ 65.30            
Granted - average exercise price $ 110            
Exercised average exercise price $ 53.00            
Cancelled or Expired average exercise price $ 99.26            
Outstanding at March 31, 2012 average exercise price $ 71.65            
Exercisable at March 31, 2012 average exercise price $ 63.06            
Average Remaining Life (years) [Abstract]              
Outstanding at March 31, 2012 average remaining life 6.0            
Exercisable at March 31, 2012 average remaining life 5.1            
Black Scholes Option Pricing model assumptions [Abstract]              
Dividend yield 2.00% 2.00%          
Volatility 22.50% 22.30%          
Risk-free interest rate 0.86% 2.20%          
Expected term (years) 5 5          
Number of Options (000s) [Abstract]              
Stock Options Outstanding at January 1, 2012 13,540            
Stock Options Granted 1,635            
Stock Options Exercised During Period (1,294)            
Stock Options Cancelled or Expired (11)            
Stock Options Outstanding at March 31, 2012 13,870            
Stock Options Exercisable at March 31, 2012 10,722            
Share Based Compenation Additional Information [Abstract]              
Unrecognized compensation expense       44,000,000 51,000,000   10,000,000
Recognition period remaining       1.2      
Performance based awards vesting, as a percentage of the target, low end of range         0.00%    
Performance based awards vesting, as a percentage of the target, high end of range         150.00%    
Non-vested at January 1, 2012         962   340
Granted     89   401    
Vested         (507)   (87)
Cancelled         (2)   (7)
Non-vested at March 31, 2012         854   246
Non-vested at January 1, 2012         $ 71.58   $ 75.51
Granted average grant date fair value     $ 109   $ 103 $ 92.06  
Vested average grant date fair value         $ 56.30   $ 61.20
Cancelled average grant date fair value         $ 89.37   $ 75.82
Non-vested at March 31, 2012         $ 88.86   $ 80.61
Performance Period         3 Years   3 Years
Share Based Compensation Cost Recognition Period         through the first quarter of 2015   through the first quarter of 2017
Stock Options Additional Information [Abstract]              
Weighted-average fair values of options granted $ 17.46 $ 17.70          
Total intrinsic value of stock options exercised 74,000,000 69,000,000          
Cash received from option exercises 69,000,000 73,000,000          
Excess tax benefit on stock option exercises 32,000,000 18,000,000          
Cash tax benefit realized from stock option exercises $ 46,000,000 $ 24,000,000