Exhibit 23.1

CONSENT OF INDEPENDENT REGISTERED PUBLIC ACCOUNTING FIRM

We consent to the incorporation by reference in Registration Statement No. 333-151942 of Potash Corporation of Saskatchewan Inc. on Form S-8 of our report dated June 18, 2010, relating to the financial statements appearing in this Annual Report on Form 11-K of the White Springs Agricultural Chemicals, Inc. Savings and Investment Plan for Collective Bargaining Employees for the year ended December 31, 2009.

/s/  Deloitte & Touche LLP

Chicago, Illinois

June 18, 2010