X0306 4 2013-10-22 0 0000776008 STAR SCIENTIFIC INC STSI 0001504151 Haynes Burton J. C/O STAR SCIENTIFIC, INC. 4470 COX ROAD, SUITE 110 GLEN ALLEN VA 23060 1 0 0 0 Employee Stock Option (right to buy) 1.90 2013-10-22 4 A 0 50000 0 A 2013-10-22 2023-10-22 Common Stock 50000 50000 D Stock options issued under the Issuer's 2008 Incentive Award Plan and were granted to Reporting Person on October 22, 2013. The option shares are fully vested. The Reporting Person has the right to acquire an additional 200,000 shares of common stock upon exercise of currently outstanding stock options with exercise prices and expiration dates that differ from that of options reported above. /s/ Burton J. Haynes 2013-10-22