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Inventories - Schedule of Inventory Components (Detail) (USD $)
In Millions, unless otherwise specified
Jun. 30, 2014
Dec. 31, 2013
Inventory Disclosure [Abstract]    
Finished goods $ 688 $ 578
Work-in-process 1,077 828
Bauxite and alumina 642 581
Purchased raw materials 584 474
Operating supplies 236 244
Inventories, total $ 3,227 $ 2,705