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Goodwill and Intangible Assets (Schedule of Goodwill by Segment) (Details) (USD $)
In Millions, unless otherwise specified
12 Months Ended
Sep. 30, 2012
Sep. 30, 2011
Goodwill [Line Items]    
Goodwill, Beginning Balance $ 796.2 $ 816.9
Goodwill, Acquisitions and Adjustments 765.4 4.9
Goodwill, Currency Translation and Other 36.8 (25.6)
Goodwill, Ending Balance 1,598.4 796.2
Merchant Gases [Member]
   
Goodwill [Line Items]    
Goodwill, Beginning Balance 479.2 498.0
Goodwill, Acquisitions and Adjustments 630.0 4.9
Goodwill, Currency Translation and Other 29.4 (23.7)
Goodwill, Ending Balance 1,138.6 479.2
Tonnage Gases [Member]
   
Goodwill [Line Items]    
Goodwill, Beginning Balance 14.1 15.5
Goodwill, Acquisitions and Adjustments 0 0
Goodwill, Currency Translation and Other 0.6 (1.4)
Goodwill, Ending Balance 14.7 14.1
Electronics and Performance Materials [Member]
   
Goodwill [Line Items]    
Goodwill, Beginning Balance 302.9 303.4
Goodwill, Acquisitions and Adjustments 135.4 0
Goodwill, Currency Translation and Other 6.8 (0.5)
Goodwill, Ending Balance $ 445.1 $ 302.9