Exhibit 23.5

Gaffney, Cline & Associates, Inc.

5555 San Felipe Street

Suite 550

Houston, TX 77056, USA

Telephone: +1 713 850 9955

www.gaffney-cline.com

March 27, 2020

Board of directors

Ecopetrol S.A.

Calle 13 No. 36 -34

Bogotá, D.C.

Colombia

CONSENT OF GAFFNEY, CLINE & ASSOCIATES

Dear Sirs,

As independent reserve engineers for Ecopetrol S.A.(Ecopetrol), Gaffney, Cline & Associates (GCA) hereby confirms that it has granted and not withdrawn its consent to (i) the references to GCA and to the inclusion of information contained in our third-party letter report entitled “ SEC Proved Reserves Statement for Forty Nine Fields in Colombia as of December 31, 2019”, dated February 24, 2020, prepared for Ecopetrol, and to the annexation of our report as an exhibit in Ecopetrol’s annual report on Form 20-F for the year ended December 31, 2019 , and (ii) incorporation by reference of this consent and our report into Ecopetrol S.A.’s registration statement on Form F-3 filed with the United States Securities and Exchange Commission on June 1, 2018 (the “Registration Statement”).

Yours sincerely

GAFFNEY, CLINE & ASSOCIATES, INC.

/s/ Daniel Amitrano

Project Manager

Daniel Amitrano, Principal Advisor