<?xml version="1.0"?>
<ownershipDocument>

    <schemaVersion>X0203</schemaVersion>

    <documentType>3</documentType>

    <periodOfReport>2010-09-08</periodOfReport>

    <noSecuritiesOwned>0</noSecuritiesOwned>

    <issuer>
        <issuerCik>0001368265</issuerCik>
        <issuerName>Clean Energy Fuels Corp.</issuerName>
        <issuerTradingSymbol>CLNE</issuerTradingSymbol>
    </issuer>

    <reportingOwner>
        <reportingOwnerId>
            <rptOwnerCik>0001500770</rptOwnerCik>
            <rptOwnerName>Bacon John R.</rptOwnerName>
        </reportingOwnerId>
        <reportingOwnerAddress>
            <rptOwnerStreet1>C/O CLEAN ENERGY FUELS CORP.</rptOwnerStreet1>
            <rptOwnerStreet2>3020 OLD RANCH PARKWAY #400</rptOwnerStreet2>
            <rptOwnerCity>SEAL BEACH</rptOwnerCity>
            <rptOwnerState>CA</rptOwnerState>
            <rptOwnerZipCode>90740</rptOwnerZipCode>
            <rptOwnerStateDescription></rptOwnerStateDescription>
        </reportingOwnerAddress>
        <reportingOwnerRelationship>
            <isDirector>0</isDirector>
            <isOfficer>1</isOfficer>
            <isTenPercentOwner>0</isTenPercentOwner>
            <isOther>0</isOther>
            <officerTitle>President, BAF Tech.</officerTitle>
            <otherText></otherText>
        </reportingOwnerRelationship>
    </reportingOwner>

    <nonDerivativeTable></nonDerivativeTable>

    <derivativeTable>
        <derivativeHolding>
            <securityTitle>
                <value>Stock Option (Right to Buy)</value>
            </securityTitle>
            <conversionOrExercisePrice>
                <value>14.06</value>
            </conversionOrExercisePrice>
            <exerciseDate>
                <footnoteId id="F1"/>
            </exerciseDate>
            <expirationDate>
                <value>2019-10-09</value>
            </expirationDate>
            <underlyingSecurity>
                <underlyingSecurityTitle>
                    <value>Common Stock</value>
                </underlyingSecurityTitle>
                <underlyingSecurityShares>
                    <value>25000</value>
                </underlyingSecurityShares>
            </underlyingSecurity>
            <ownershipNature>
                <directOrIndirectOwnership>
                    <value>D</value>
                </directOrIndirectOwnership>
            </ownershipNature>
        </derivativeHolding>
    </derivativeTable>

    <footnotes>
        <footnote id="F1">The stock option was granted to the reporting person under the Issuer's Amended &amp; Restated 2006 Equity Incentive Plan.  The stock option vests as to 34% of the total shares subject to the stock option upon the first anniversary of the date of grant, and 33% on each anniversary thereafter until the stock option is fully vested.</footnote>
    </footnotes>

    <ownerSignature>
        <signatureName>/S/ Mitchell W. Pratt, Attorney-in-Fact</signatureName>
        <signatureDate>2010-09-10</signatureDate>
    </ownerSignature>
</ownershipDocument>
