2.4.0.6 Html 175 351 1 false 56 0 false 5 false false R1.htm 001 - Document - Document and Entity Information Sheet http://www.xxiicentury.com/role/DocumentAndEntityInformation Document and Entity Information true false R2.htm 002 - Statement - CONSOLIDATED BALANCE SHEETS Sheet http://www.xxiicentury.com/role/ConsolidatedBalanceSheets CONSOLIDATED BALANCE SHEETS false false R3.htm 003 - Statement - CONSOLIDATED BALANCE SHEETS (Parenthetical) Sheet http://www.xxiicentury.com/role/ConsolidatedBalanceSheetsParenthetical CONSOLIDATED BALANCE SHEETS (Parenthetical) false false R4.htm 004 - Statement - CONSOLIDATED STATEMENTS OF OPERATIONS Sheet http://www.xxiicentury.com/role/ConsolidatedStatementsOfOperations CONSOLIDATED STATEMENTS OF OPERATIONS false false R5.htm 005 - Statement - CONSOLIDATED STATEMENT OF SHAREHOLDERS' DEFICIT Sheet http://www.xxiicentury.com/role/ConsolidatedStatementOfShareholdersDeficit CONSOLIDATED STATEMENT OF SHAREHOLDERS' DEFICIT false false R6.htm 006 - Disclosure - CONSOLIDATED STATEMENTS OF SHAREHOLDERS' DEFICIT (Parenthetical) Sheet http://www.xxiicentury.com/role/ConsolidatedStatementsOfShareholdersDeficitParenthetical CONSOLIDATED STATEMENTS OF SHAREHOLDERS' DEFICIT (Parenthetical) false false R7.htm 007 - Statement - CONSOLIDATED STATEMENTS OF CASH FLOWS Sheet http://www.xxiicentury.com/role/ConsolidatedStatementsOfCashFlows CONSOLIDATED STATEMENTS OF CASH FLOWS false false R8.htm 101 - Disclosure - NATURE OF BUSINESS AND SUMMARY OF SIGNIFICANT ACCOUNTING POLICIES Sheet http://www.xxiicentury.com/role/NatureOfBusinessAndSummaryOfSignificantAccountingPolicies NATURE OF BUSINESS AND SUMMARY OF SIGNIFICANT ACCOUNTING POLICIES false false R9.htm 102 - Disclosure - LIQUIDITY AND MANAGEMENT'S PLANS Sheet http://www.xxiicentury.com/role/LiquidityAndManagementsPlans LIQUIDITY AND MANAGEMENT'S PLANS false false R10.htm 103 - Disclosure - MAY and NOVEMBER 2012 PRIVATE PLACEMENT Sheet http://www.xxiicentury.com/role/MayAndNovemberTwoZeroOneTwoPrivatePlacement MAY and NOVEMBER 2012 PRIVATE PLACEMENT false false R11.htm 104 - Disclosure - AMOUNTS OWED NORTH CAROLINA STATE UNIVERSITY ("NCSU") Sheet http://www.xxiicentury.com/role/AmountsOwedNorthCarolinaStateUniversityNcsu AMOUNTS OWED NORTH CAROLINA STATE UNIVERSITY ("NCSU") false false R12.htm 105 - Disclosure - DEMAND BANK LOAN Sheet http://www.xxiicentury.com/role/DemandBankLoan DEMAND BANK LOAN false false R13.htm 106 - Disclosure - NOTES PAYABLE Notes http://www.xxiicentury.com/role/NotesPayable NOTES PAYABLE false false R14.htm 107 - Disclosure - CONVERTIBLE NOTES Notes http://www.xxiicentury.com/role/ConvertibleNotes CONVERTIBLE NOTES false false R15.htm 108 - Disclosure - DUE FROM RELATED PARTY Sheet http://www.xxiicentury.com/role/DueFromRelatedParty DUE FROM RELATED PARTY false false R16.htm 109 - Disclosure - DUE FROM OFFICERS Sheet http://www.xxiicentury.com/role/DueFromOfficers DUE FROM OFFICERS false false R17.htm 110 - Disclosure - WARRANTS FOR COMMON STOCK Sheet http://www.xxiicentury.com/role/WarrantsForCommonStock WARRANTS FOR COMMON STOCK false false R18.htm 111 - Disclosure - COMMITMENTS Sheet http://www.xxiicentury.com/role/Commitments COMMITMENTS false false R19.htm 112 - Disclosure - EARNINGS PER COMMON SHARE Sheet http://www.xxiicentury.com/role/EarningsPerCommonShare EARNINGS PER COMMON SHARE false false R20.htm 113 - Disclosure - STOCK BASED COMPENSATION Sheet http://www.xxiicentury.com/role/StockBasedCompensation STOCK BASED COMPENSATION false false R21.htm 114 - Disclosure - INCOME TAXES Sheet http://www.xxiicentury.com/role/IncomeTaxes INCOME TAXES false false R22.htm 115 - Disclosure - SUBSEQUENT EVENT Sheet http://www.xxiicentury.com/role/SubsequentEvent SUBSEQUENT EVENT false false R23.htm 201 - Disclosure - NATURE OF BUSINESS AND SUMMARY OF SIGNIFICANT ACCOUNTING POLICIES (Policy) Sheet http://www.xxiicentury.com/role/NatureOfBusinessAndSummaryOfSignificantAccountingPoliciesPolicy NATURE OF BUSINESS AND SUMMARY OF SIGNIFICANT ACCOUNTING POLICIES (Policy) false false R24.htm 306 - Disclosure - NOTES PAYABLE (Tables) Notes http://www.xxiicentury.com/role/NotesPayableTables NOTES PAYABLE (Tables) false false R25.htm 307 - Disclosure - CONVERTIBLE NOTES (Tables) Notes http://www.xxiicentury.com/role/ConvertibleNotesTables CONVERTIBLE NOTES (Tables) false false R26.htm 310 - Disclosure - WARRANTS FOR COMMON STOCK (Tables) Sheet http://www.xxiicentury.com/role/WarrantsForCommonStockTables WARRANTS FOR COMMON STOCK (Tables) false false R27.htm 311 - Disclosure - COMMITMENTS (Tables) Sheet http://www.xxiicentury.com/role/CommitmentsTables COMMITMENTS (Tables) false false R28.htm 312 - Disclosure - EARNINGS PER COMMON SHARE (Tables) Sheet http://www.xxiicentury.com/role/EarningsPerCommonShareTables EARNINGS PER COMMON SHARE (Tables) false false R29.htm 313 - Disclosure - STOCK BASED COMPENSATION (Tables) Sheet http://www.xxiicentury.com/role/StockBasedCompensationTables STOCK BASED COMPENSATION (Tables) false false R30.htm 314 - Disclosure - INCOME TAXES (Tables) Sheet http://www.xxiicentury.com/role/IncomeTaxesTables INCOME TAXES (Tables) false false R31.htm 40101 - Disclosure - NATURE OF BUSINESS AND SUMMARY OF SIGNIFICANT ACCOUNTING POLICIES (Narrative) (Details) Sheet http://www.xxiicentury.com/role/NatureOfBusinessAndSummaryOfSignificantAccountingPoliciesNarrativeDetails NATURE OF BUSINESS AND SUMMARY OF SIGNIFICANT ACCOUNTING POLICIES (Narrative) (Details) false false R32.htm 40102 - Disclosure - NATURE OF BUSINESS AND SUMMARY OF SIGNIFICANT ACCOUNTING POLICIES (Inventory) (Details) Sheet http://www.xxiicentury.com/role/NatureOfBusinessAndSummaryOfSignificantAccountingPoliciesInventoryDetails NATURE OF BUSINESS AND SUMMARY OF SIGNIFICANT ACCOUNTING POLICIES (Inventory) (Details) false false R33.htm 40201 - Disclosure - LIQUIDITY AND MANAGEMENT'S PLANS (Details) Sheet http://www.xxiicentury.com/role/LiquidityAndManagementsPlansDetails LIQUIDITY AND MANAGEMENT'S PLANS (Details) false false R34.htm 40301 - Disclosure - MAY and NOVEMBER 2012 PRIVATE PLACEMENT (Details) Sheet http://www.xxiicentury.com/role/MayAndNovemberTwoZeroOneTwoPrivatePlacementDetails MAY and NOVEMBER 2012 PRIVATE PLACEMENT (Details) false false R35.htm 40401 - Disclosure - AMOUNTS OWED NORTH CAROLINA STATE UNIVERSITY ("NCSU") (Details) Sheet http://www.xxiicentury.com/role/AmountsOwedNorthCarolinaStateUniversityNcsuDetails AMOUNTS OWED NORTH CAROLINA STATE UNIVERSITY ("NCSU") (Details) false false R36.htm 40501 - Disclosure - DEMAND BANK LOAN (Details) Sheet http://www.xxiicentury.com/role/DemandBankLoanDetails DEMAND BANK LOAN (Details) false false R37.htm 40601 - Disclosure - NOTES PAYABLE (Notes Payable) (Details) Notes http://www.xxiicentury.com/role/NotesPayableNotesPayableDetails NOTES PAYABLE (Notes Payable) (Details) false false R38.htm 40602 - Disclosure - NOTES PAYABLE (Narrative) (Details) Notes http://www.xxiicentury.com/role/NotesPayableNarrativeDetails NOTES PAYABLE (Narrative) (Details) false false R39.htm 40701 - Disclosure - CONVERTIBLE NOTES (Narrative) (Details) Notes http://www.xxiicentury.com/role/ConvertibleNotesNarrativeDetails CONVERTIBLE NOTES (Narrative) (Details) false false R40.htm 40702 - Disclosure - CONVERTIBLE NOTES (Summary of Notes and Related Discount) (Details) Notes http://www.xxiicentury.com/role/ConvertibleNotesSummaryOfNotesAndRelatedDiscountDetails CONVERTIBLE NOTES (Summary of Notes and Related Discount) (Details) false false R41.htm 40801 - Disclosure - DUE FROM RELATED PARTY (Details) Sheet http://www.xxiicentury.com/role/DueFromRelatedPartyDetails DUE FROM RELATED PARTY (Details) false false R42.htm 40901 - Disclosure - DUE FROM OFFICERS (Details) Sheet http://www.xxiicentury.com/role/DueFromOfficersDetails DUE FROM OFFICERS (Details) false false R43.htm 41001 - Disclosure - WARRANTS FOR COMMON STOCK (Narrative) (Details) Sheet http://www.xxiicentury.com/role/WarrantsForCommonStockNarrativeDetails WARRANTS FOR COMMON STOCK (Narrative) (Details) false false R44.htm 41002 - Disclosure - WARRANTS FOR COMMON STOCK (Roll-Forward of Warrant Liabilitiy from Initial Valuation) (Details) Sheet http://www.xxiicentury.com/role/WarrantsForCommonStockRollforwardOfWarrantLiabilitiyFromInitialValuationDetails WARRANTS FOR COMMON STOCK (Roll-Forward of Warrant Liabilitiy from Initial Valuation) (Details) false false R45.htm 41003 - Disclosure - WARRANTS FOR COMMON STOCK (Warrant Activity) (Details) Sheet http://www.xxiicentury.com/role/WarrantsForCommonStockWarrantActivityDetails WARRANTS FOR COMMON STOCK (Warrant Activity) (Details) false false R46.htm 41101 - Disclosure - COMMITMENTS (Narrative) (Details) Sheet http://www.xxiicentury.com/role/CommitmentsNarrativeDetails COMMITMENTS (Narrative) (Details) false false R47.htm 41102 - Disclosure - COMMITMENTS (Schedule Rent) (Details) Sheet http://www.xxiicentury.com/role/CommitmentsScheduleRentDetails COMMITMENTS (Schedule Rent) (Details) false false R48.htm 41201 - Disclosure - EARNINGS PER COMMON SHARE (Computation of Basic and Diluted Earnings Per Common Share) (Details) Sheet http://www.xxiicentury.com/role/EarningsPerCommonShareComputationOfBasicAndDilutedEarningsPerCommonShareDetails EARNINGS PER COMMON SHARE (Computation of Basic and Diluted Earnings Per Common Share) (Details) false false R49.htm 41202 - Disclosure - EARNINGS PER COMMON SHARE (Anti-Dilutive Securities Outstanding Excluded from Computation) (Details) Sheet http://www.xxiicentury.com/role/EarningsPerCommonShareAntidilutiveSecuritiesOutstandingExcludedFromComputationDetails EARNINGS PER COMMON SHARE (Anti-Dilutive Securities Outstanding Excluded from Computation) (Details) false false R50.htm 41301 - Disclosure - STOCK BASED COMPENSATION (Narrative) (Details) Sheet http://www.xxiicentury.com/role/StockBasedCompensationNarrativeDetails STOCK BASED COMPENSATION (Narrative) (Details) false false R51.htm 41302 - Disclosure - STOCK BASED COMPENSATION (Schedule of Fair Value Assumptions) (Details) Sheet http://www.xxiicentury.com/role/StockBasedCompensationScheduleOfFairValueAssumptionsDetails STOCK BASED COMPENSATION (Schedule of Fair Value Assumptions) (Details) false false R52.htm 41303 - Disclosure - STOCK BASED COMPENSATION (Summary of All Stock Option Activity) (Details) Sheet http://www.xxiicentury.com/role/StockBasedCompensationSummaryOfAllStockOptionActivityDetails STOCK BASED COMPENSATION (Summary of All Stock Option Activity) (Details) false false R53.htm 41401 - Disclosure - INCOME TAXES (Schedule of Provision (Benefit) for Income Taxes) (Details) Sheet http://www.xxiicentury.com/role/IncomeTaxesScheduleOfProvisionBenefitForIncomeTaxesDetails INCOME TAXES (Schedule of Provision (Benefit) for Income Taxes) (Details) false false R54.htm 41402 - Disclosure - INCOME TAXES (Schedule of Reconciliation of Income Taxes) (Details) Sheet http://www.xxiicentury.com/role/IncomeTaxesScheduleOfReconciliationOfIncomeTaxesDetails INCOME TAXES (Schedule of Reconciliation of Income Taxes) (Details) false false R55.htm 41403 - Disclosure - INCOME TAXES (Schedule of Deferred Tax Assets and Liabilities) (Details) Sheet http://www.xxiicentury.com/role/IncomeTaxesScheduleOfDeferredTaxAssetsAndLiabilitiesDetails INCOME TAXES (Schedule of Deferred Tax Assets and Liabilities) (Details) false false R56.htm 41404 - Disclosure - INCOME TAXES (Narrative) (Details) Sheet http://www.xxiicentury.com/role/IncomeTaxesNarrativeDetails INCOME TAXES (Narrative) (Details) false false R57.htm 41501 - Disclosure - SUBSEQUENT EVENT (Details) Sheet http://www.xxiicentury.com/role/SubsequentEventDetails SUBSEQUENT EVENT (Details) false false All Reports Book All Reports Element us-gaap_ClassOfWarrantOrRightExercisePriceOfWarrantsOrRights had a mix of decimals attribute values: 1 2. Element us-gaap_DebtInstrumentConvertibleConversionPrice1 had a mix of decimals attribute values: 2 4. Element us-gaap_DebtInstrumentInterestRateStatedPercentage had a mix of decimals attribute values: 1 2. Element us-gaap_ShareBasedCompensationArrangementByShareBasedPaymentAwardFairValueAssumptionsRiskFreeInterestRate had a mix of decimals attribute values: 3 4. Element us-gaap_ShareBasedCompensationArrangementByShareBasedPaymentAwardOptionsOutstandingWeightedAverageExercisePrice had a mix of decimals attribute values: 1 2. Element us-gaap_ShareBasedCompensationArrangementsByShareBasedPaymentAwardOptionsGrantsInPeriodWeightedAverageExercisePrice had a mix of decimals attribute values: 1 2. Element us-gaap_SharePrice had a mix of decimals attribute values: 1 2. Element xxii_CommissionPercentage had a mix of decimals attribute values: 1 2. Element xxii_DebtConversionConvertedInstrumentWarrantsIssuedNumberOfSecuritiesCalledByWarrantsOrRightsAsPercentageOfOutstandingPrincipalBadExtended had a mix of decimals attribute values: 1 2. Process Flow-Through: 002 - Statement - CONSOLIDATED BALANCE SHEETS Process Flow-Through: Removing column 'Jan. 25, 2011' Process Flow-Through: Removing column 'Dec. 31, 2010' Process Flow-Through: 003 - Statement - CONSOLIDATED BALANCE SHEETS (Parenthetical) Process Flow-Through: 004 - Statement - CONSOLIDATED STATEMENTS OF OPERATIONS Process Flow-Through: 007 - Statement - CONSOLIDATED STATEMENTS OF CASH FLOWS xxii-20121231.xml xxii-20121231.xsd xxii-20121231_cal.xml xxii-20121231_def.xml xxii-20121231_lab.xml xxii-20121231_pre.xml true true