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Derivative Financial Instruments (Details) (USD $)
3 Months Ended 9 Months Ended
Sep. 30, 2014
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Sep. 30, 2013
Sep. 30, 2014
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Sep. 30, 2013
Dec. 31, 2013
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Dec. 31, 2012
Fair values of derivatives on consolidated balance sheets            
Maximum period covering risk of changes in supply of gas prices     18 months      
Open derivative contracts for natural gas (in MMBtus) 117,200,000   117,200,000   76,300,000  
Percentage of natural gas consumption covered by derivatives     85.00%      
Aggregate fair value of the derivative instruments with credit risk related contingent features in a net liability position $ 20,400,000   $ 20,400,000   $ 200,000  
Authorized expenditure for construction of new ammonia and urea/UAN production units           3,800,000,000
Unrealized (losses) gains            
Derivatives not designated as hedges (15,500,000) 14,300,000 (79,900,000) 10,800,000    
Cash flow hedge ineffectiveness   1,300,000   (800,000)    
Total unrealized (losses) gains (15,500,000) 15,600,000 (79,900,000) 10,000,000    
Realized gains (20,100,000) (7,400,000) 77,400,000 1,900,000    
Net derivative (losses) gains (35,600,000) 8,200,000 (2,500,000) 11,900,000    
Cash collateral on deposit with derivative counterparties 0   0   0  
Foreign exchange contracts
           
Fair values of derivatives on consolidated balance sheets            
Notional amount of derivative 328,400,000   328,400,000   636,300,000  
Derivatives not designated as cash flow hedges
           
Unrealized (losses) gains            
Derivatives not designated as hedges (15,500,000) 14,300,000 (79,900,000) 10,800,000    
Derivatives not designated as cash flow hedges | Natural gas derivatives | Cost of Sales
           
Unrealized (losses) gains            
Derivatives not designated as hedges 12,100,000 (5,600,000) (39,100,000) (1,200,000)    
Derivatives not designated as cash flow hedges | Foreign exchange contracts | Other operating - net
           
Unrealized (losses) gains            
Derivatives not designated as hedges (27,600,000) 19,900,000 (40,800,000) 12,000,000    
Derivatives designated as cash flow hedges | Foreign exchange contracts
           
Fair values of derivatives on consolidated balance sheets            
Notional amount of derivative 0   0      
Gain (loss) recognized in OCI   6,100,000   (400,000)    
Gain (loss) reclassified from AOCI into income 2,800,000          
Derivatives designated as cash flow hedges | Foreign exchange contracts | Other operating - net
           
Unrealized (losses) gains            
Net derivative (losses) gains   $ 1,300,000   $ (800,000)