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Derivative Financial Instruments (Details) (USD $)
3 Months Ended 6 Months Ended 3 Months Ended 6 Months Ended 12 Months Ended 3 Months Ended 6 Months Ended 3 Months Ended 6 Months Ended 3 Months Ended 6 Months Ended 3 Months Ended 6 Months Ended
Jun. 30, 2014
MMBTU
Jun. 30, 2013
Jun. 30, 2014
MMBTU
Jun. 30, 2013
Dec. 31, 2013
MMBTU
Dec. 31, 2012
Jun. 30, 2014
Foreign exchange contracts
Jun. 30, 2013
Derivatives designated as cash flow hedges
Foreign exchange contracts
Jun. 30, 2014
Derivatives designated as cash flow hedges
Foreign exchange contracts
Jun. 30, 2013
Derivatives designated as cash flow hedges
Foreign exchange contracts
Dec. 31, 2013
Derivatives designated as cash flow hedges
Foreign exchange contracts
Jun. 30, 2013
Derivatives designated as cash flow hedges
Foreign exchange contracts
Other operating - net
Jun. 30, 2013
Derivatives designated as cash flow hedges
Foreign exchange contracts
Other operating - net
Jun. 30, 2014
Derivatives not designated as cash flow hedges
Jun. 30, 2013
Derivatives not designated as cash flow hedges
Jun. 30, 2014
Derivatives not designated as cash flow hedges
Jun. 30, 2013
Derivatives not designated as cash flow hedges
Jun. 30, 2014
Derivatives not designated as cash flow hedges
Natural gas derivatives
Cost of sales
Jun. 30, 2013
Derivatives not designated as cash flow hedges
Natural gas derivatives
Cost of sales
Jun. 30, 2014
Derivatives not designated as cash flow hedges
Natural gas derivatives
Cost of sales
Jun. 30, 2013
Derivatives not designated as cash flow hedges
Natural gas derivatives
Cost of sales
Jun. 30, 2014
Derivatives not designated as cash flow hedges
Foreign exchange contracts
Other operating - net
Jun. 30, 2013
Derivatives not designated as cash flow hedges
Foreign exchange contracts
Other operating - net
Jun. 30, 2014
Derivatives not designated as cash flow hedges
Foreign exchange contracts
Other operating - net
Jun. 30, 2013
Derivatives not designated as cash flow hedges
Foreign exchange contracts
Other operating - net
Fair values of derivatives on consolidated statements of operations                                                  
Maximum period covering risk of changes in supply of gas prices     18 months                                            
Open derivative contracts for natural gas (in MMBtus) 55,300,000   55,300,000   76,300,000                                        
Percentage of natural gas consumption covered by derivatives     82.00%                                            
Aggregate fair value of the derivative instruments with credit-risk-related contingent features in a net liability position $ 3,200,000   $ 3,200,000   $ 200,000                                        
Authorized expenditure for construction of new ammonia and urea/UAN production units           3,800,000,000                                      
Notional amount of derivative             464,200,000   0                                
Gain (loss) reclassified from AOCI into income                 0   0                            
Net gain (loss) expected to be reclassified into earnings from AOCI                 0                                
Gain (loss) recognized in OCI               5,700,000   (6,500,000)                              
Unrealized gains (losses)                                                  
Derivatives not designated as hedges (36,900,000) (12,400,000) (64,400,000) (3,500,000)                   (36,900,000) (12,400,000) (64,400,000) (3,500,000) (28,600,000) (18,000,000) (51,200,000) 4,400,000 (8,300,000) 5,600,000 (13,200,000) (7,900,000)
Cash flow hedge ineffectiveness   (2,000,000)   (2,100,000)                                          
Total unrealized gains (losses) (36,900,000) (14,400,000) (64,400,000) (5,600,000)                                          
Realized gains (losses) 35,500,000 17,000,000 97,500,000 9,300,000                                          
Net derivative gains (losses) (1,400,000) 2,600,000 33,100,000 3,700,000               (2,000,000) (2,100,000)                        
Cash collateral on deposit with derivative counterparties $ 0   $ 0   $ 0