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        <name>MET TRANSPRTN AUTH NY REVENUE</name>
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        <name>NEW YORK CNTYS NY TOBACCO TRUS</name>
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        <name>NEW JERSEY ST ECON DEV AUTH SC</name>
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      <invstOrSec>
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        <valUSD>13537929.00000000</valUSD>
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      <invstOrSec>
        <name>MET TRANSPRTN AUTH NY REVENUE</name>
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          <isin value="US59261AJ991"/>
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      <invstOrSec>
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          <isin value="US45204FEN15"/>
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        <debtSec>
          <maturityDt>2052-11-15</maturityDt>
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        <name>NEW YORK CNTYS NY TOBACCO TRUS</name>
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        <valUSD>2338450.00000000</valUSD>
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        <name>ILLINOIS ST FIN AUTH REVENUE</name>
        <lei>549300ZG6UBPNNNRN315</lei>
        <title>Illinois Finance Authority</title>
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          <isin value="US45204FEP62"/>
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        <curCd>USD</curCd>
        <valUSD>781207.00000000</valUSD>
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        <assetCat>DBT</assetCat>
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        <fairValLevel>2</fairValLevel>
        <debtSec>
          <maturityDt>2052-11-15</maturityDt>
          <couponKind>Variable</couponKind>
          <annualizedRt>4.00000000</annualizedRt>
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          <areIntrstPmntsInArrs>Y</areIntrstPmntsInArrs>
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          <isCashCollateral>N</isCashCollateral>
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        <name>TOBACCO SETTLEMENT FING CORP V</name>
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          <isin value="US88880NAU37"/>
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        <balance>5000000.00000000</balance>
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        <curCd>USD</curCd>
        <valUSD>4687500.00000000</valUSD>
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        <assetCat>DBT</assetCat>
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        <invCountry>US</invCountry>
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        <fairValLevel>2</fairValLevel>
        <debtSec>
          <maturityDt>2047-06-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>5.00000000</annualizedRt>
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        <securityLending>
          <isCashCollateral>N</isCashCollateral>
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      <invstOrSec>
        <name>MASSACHUSETTS ST DEV FIN AGY R</name>
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        <title>Massachusetts Development Finance Agency</title>
        <cusip>57583UVQ8</cusip>
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          <isin value="US57583UVQ83"/>
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        <balance>3000000.00000000</balance>
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        <curCd>USD</curCd>
        <valUSD>2905200.00000000</valUSD>
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          <maturityDt>2044-07-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>5.00000000</annualizedRt>
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      <invstOrSec>
        <name>PUERTO RICO SALES TAX FING COR</name>
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          <isin value="US74529JPX71"/>
          <other otherDesc="SEDOL" value="BJHMV19"/>
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        <name>NEW HAMPSHIRE ST HLTH &amp; EDU FA</name>
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        <name>CALIFORNIA STWD CMNTYS DEV AUT</name>
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          <maturityDt>2058-12-01</maturityDt>
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          <annualizedRt>5.50000000</annualizedRt>
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        <name>S WSTRN IL DEV AUTH REV</name>
        <lei>549300B1KLLJ8NU5XK71</lei>
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          <isin value="US84552YFD85"/>
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        <valUSD>521250.00000000</valUSD>
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        <name>WESTCHESTER CNTY NY HLTHCARE C</name>
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        <name>NEW YORK ST URBAN DEV CORP SAL</name>
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        <name>PUERTO RICO SALES TAX FING COR</name>
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          <isin value="US74529JRL16"/>
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        <name>DOMINION WTR &amp; SANTN DIST CO R</name>
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        <name>PHOENIX AZ INDL DEV AUTH MF HS</name>
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        <name>MET TRANSPRTN AUTH NY REVENUE</name>
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        <name>OROVILLE CA REVENUE</name>
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        <name>MARYLAND ST TRANSPRTN AUTH TRA</name>
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        <name>ILLINOIS ST FIN AUTH REVENUE</name>
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        <valUSD>2965320.00000000</valUSD>
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          <annualizedRt>5.50000000</annualizedRt>
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          <isCashCollateral>N</isCashCollateral>
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        <name>ILLINOIS ST FIN AUTH REVENUE</name>
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        <identifiers>
          <isin value="US45204EC300"/>
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        <valUSD>2735775.00000000</valUSD>
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        <debtSec>
          <maturityDt>2042-05-15</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>5.25000000</annualizedRt>
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        <securityLending>
          <isCashCollateral>N</isCashCollateral>
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        <name>ARLINGTON TX HGR EDU FIN CORP</name>
        <lei>N/A</lei>
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        <cusip>041806AM2</cusip>
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        <valUSD>1011710.00000000</valUSD>
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        <invCountry>US</invCountry>
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        <debtSec>
          <maturityDt>2034-03-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>7.00000000</annualizedRt>
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          <areIntrstPmntsInArrs>N</areIntrstPmntsInArrs>
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        <securityLending>
          <isCashCollateral>N</isCashCollateral>
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        <name>OREGON ST HLTH &amp; SCIENCE UNIV</name>
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        <title>Oregon Health &amp; Science University</title>
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          <maturityDt>2051-07-01</maturityDt>
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          <annualizedRt>3.00000000</annualizedRt>
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      </invstOrSec>
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        <name>TENDER OPTION BOND TRUST RECEI</name>
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        <identifiers>
          <isin value="US88034MR573"/>
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        <balance>4225000.00000000</balance>
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        <curCd>USD</curCd>
        <valUSD>4385381.00000000</valUSD>
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        <debtSec>
          <maturityDt>2038-01-01</maturityDt>
          <couponKind>Variable</couponKind>
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        <securityLending>
          <isCashCollateral>N</isCashCollateral>
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        <name>IOWA ST FIN AUTH MIDWSTRN DISA</name>
        <lei>549300NQVL49BTHOW391</lei>
        <title>Iowa Finance Authority</title>
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          <isin value="US46246SAE54"/>
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        <balance>9675000.00000000</balance>
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        <curCd>USD</curCd>
        <valUSD>9443767.50000000</valUSD>
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        <issuerCat>MUN</issuerCat>
        <invCountry>US</invCountry>
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        <debtSec>
          <maturityDt>2042-08-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>4.75000000</annualizedRt>
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        <securityLending>
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      </invstOrSec>
    </invstOrSecs>
    <signature>
      <ncom:dateSigned>2023-09-26</ncom:dateSigned>
      <ncom:nameOfApplicant>Pioneer Municipal High Income Fund, Inc.</ncom:nameOfApplicant>
      <ncom:signature>Anthony J. Koenig, Jr</ncom:signature>
      <ncom:signerName>Anthony J. Koenig, Jr</ncom:signerName>
      <ncom:title>Managing Director, Chief Operations Officer &amp; Treasurer of the Funds</ncom:title>
    </signature>
  </formData>
  <documents>XXXX</documents>
</edgarSubmission>
