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        <name>MET TRANSPRTN AUTH NY REVENUE</name>
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          <isin value="US59261AJ819"/>
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        <name>Multifamily Tax-Exempt Mortgag</name>
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        <name>OTERO CNTY NM COPS</name>
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          <couponKind>Variable</couponKind>
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      <invstOrSec>
        <name>RHODE ISLAND ST HLTH &amp; EDUCTNL</name>
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        <title>Rhode Island Health and Educational Building Corp</title>
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          <isin value="US762197VF55"/>
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        <curCd>USD</curCd>
        <valUSD>2252980.00000000</valUSD>
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        <assetCat>DBT</assetCat>
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        <invCountry>US</invCountry>
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        <debtSec>
          <maturityDt>2037-09-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>4.00000000</annualizedRt>
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          <isCashCollateral>N</isCashCollateral>
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      <invstOrSec>
        <name>CALIFORNIA CNTY CA TOBACCO SEC</name>
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        <title>California County Tobacco Securitization Agency</title>
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          <isin value="US13016NCT90"/>
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        <balance>10000000.00000000</balance>
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        <curCd>USD</curCd>
        <valUSD>2485800.00000000</valUSD>
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        <assetCat>DBT</assetCat>
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        <invCountry>US</invCountry>
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        <fairValLevel>2</fairValLevel>
        <debtSec>
          <maturityDt>2046-06-01</maturityDt>
          <couponKind>None</couponKind>
          <annualizedRt>0.00000000</annualizedRt>
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      <invstOrSec>
        <name>ILLINOIS ST FIN AUTH REVENUE</name>
        <lei>549300ZG6UBPNNNRN315</lei>
        <title>Illinois Finance Authority</title>
        <cusip>45204EC48</cusip>
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          <isin value="US45204EC482"/>
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        <balance>4000000.00000000</balance>
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        <curCd>USD</curCd>
        <valUSD>4220160.00000000</valUSD>
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        <debtSec>
          <maturityDt>2054-05-15</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>5.50000000</annualizedRt>
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        <title>Commonwealth of Puerto Rico</title>
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        <curCd>USD</curCd>
        <valUSD>5629500.00000000</valUSD>
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        <assetCat>DBT</assetCat>
        <issuerCat>MUN</issuerCat>
        <invCountry>US</invCountry>

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          <maturityDt>2035-07-01</maturityDt>
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          <annualizedRt>8.00000000</annualizedRt>
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        <name>PHILADELPHIA PA AUTH FOR INDL</name>
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        <title>Philadelphia Authority for Industrial Development</title>
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          <isin value="US71780CAM29"/>
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        <valUSD>1066450.00000000</valUSD>
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        <invCountry>US</invCountry>
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          <maturityDt>2050-11-15</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>5.00000000</annualizedRt>
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      <invstOrSec>
        <name>TROY NY CAPITAL RESOURCE CORP</name>
        <lei>N/A</lei>
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          <isin value="US897579BY33"/>
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        <balance>1000000.00000000</balance>
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        <curCd>USD</curCd>
        <valUSD>1144240.00000000</valUSD>
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        <assetCat>DBT</assetCat>
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        <invCountry>US</invCountry>
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          <maturityDt>2040-09-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>4.00000000</annualizedRt>
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      <invstOrSec>
        <name>PIMA CNTY AZ INDL DEV AUTH EDU</name>
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          <isin value="US72177MAM91"/>
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        <curCd>USD</curCd>
        <valUSD>24593.76000000</valUSD>
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        <assetCat>DBT</assetCat>
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        <invCountry>US</invCountry>
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        <fairValLevel>2</fairValLevel>
        <debtSec>
          <maturityDt>2031-07-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>6.75000000</annualizedRt>
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      <invstOrSec>
        <name>KING CNTY WA SCH DIST #411 ISS</name>
        <lei>N/A</lei>
        <title>King County School District No 411 Issaquah</title>
        <cusip>4952243A3</cusip>
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          <isin value="US4952243A35"/>
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        <curCd>USD</curCd>
        <valUSD>2763275.00000000</valUSD>
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        <issuerCat>MUN</issuerCat>
        <invCountry>US</invCountry>
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          <couponKind>Fixed</couponKind>
          <annualizedRt>4.00000000</annualizedRt>
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        <name>BOSTON MA</name>
        <lei>N/A</lei>
        <title>City of Boston MA</title>
        <cusip>100853ZK9</cusip>
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          <isin value="US100853ZK94"/>
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        <valUSD>2413320.00000000</valUSD>
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        <invCountry>US</invCountry>
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          <couponKind>Fixed</couponKind>
          <annualizedRt>5.00000000</annualizedRt>
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        <name>CALIFORNIA STWD CMNTYS DEV AUT</name>
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        <title>California Statewide Communities Development Authority</title>
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          <isin value="US13080SAS32"/>
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        <valUSD>1485246.00000000</valUSD>
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        <debtSec>
          <maturityDt>2033-11-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>5.62500000</annualizedRt>
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        <name>TEXAS ST MUNI GAS ACQUISITION&amp;</name>
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        <title>Texas Municipal Gas Acquisition &amp; Supply Corp III</title>
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          <isin value="US88256HBG20"/>
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          <maturityDt>2031-12-15</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>5.00000000</annualizedRt>
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        <name>ILLINOIS ST FIN AUTH REVENUE</name>
        <lei>549300ZG6UBPNNNRN315</lei>
        <title>Illinois Finance Authority</title>
        <cusip>45204EC30</cusip>
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          <isin value="US45204EC300"/>
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        <balance>3500000.00000000</balance>
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        <invCountry>US</invCountry>
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          <annualizedRt>5.25000000</annualizedRt>
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      <invstOrSec>
        <name>CONNECTICUT ST</name>
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        <title>State of Connecticut</title>
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        <valUSD>1072370.00000000</valUSD>
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          <couponKind>Fixed</couponKind>
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      <invstOrSec>
        <name>MET TRANSPRTN AUTH NY REVENUE</name>
        <lei>5493000TKYODLXADQD60</lei>
        <title>Metropolitan Transportation Authority</title>
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          <isin value="US59261AH599"/>
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        <curCd>USD</curCd>
        <valUSD>2153400.00000000</valUSD>
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        <assetCat>DBT</assetCat>
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        <invCountry>US</invCountry>
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          <maturityDt>2048-11-15</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>4.00000000</annualizedRt>
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        <name>TENDER OPTION BOND TRUST</name>
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          <couponKind>Variable</couponKind>
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        <name>UPPER OCCOQUAN VA SEWAGE AUTHR</name>
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          <isin value="US13058TAG58"/>
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      <invstOrSec>
        <name>BUCKEYE OH TOBACCO SETTLEMENT</name>
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          <isin value="US118217CZ97"/>
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        <isRestrictedSec>N</isRestrictedSec>
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          <maturityDt>2055-06-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>5.00000000</annualizedRt>
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        <name>ROCHESTER MN HLTH CARE FACS RE</name>
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          <isin value="US771902HF35"/>
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        <curCd>USD</curCd>
        <valUSD>1116310.00000000</valUSD>
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          <annualizedRt>4.00000000</annualizedRt>
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        <name>PUERTO RICO ELEC PWR AUTH PWR</name>
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          <isin value="US74526QX805"/>
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        <name>ARKANSAS ST DEV FIN AUTH INDL</name>
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          <isin value="US04108WCC47"/>
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          <maturityDt>2049-09-01</maturityDt>
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      <invstOrSec>
        <name>GEISINGER PA AUTH HLTH SYS REV</name>
        <lei>N/A</lei>
        <title>Geisinger Authority</title>
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          <isin value="US368497HP13"/>
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          <maturityDt>2045-02-15</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>5.00000000</annualizedRt>
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          <isCashCollateral>N</isCashCollateral>
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      <invstOrSec>
        <name>FAIRFAX CNTY VA</name>
        <lei>N/A</lei>
        <title>County of Fairfax VA</title>
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          <isin value="US30382AFS69"/>
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        <curCd>USD</curCd>
        <valUSD>1566348.40000000</valUSD>
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        <assetCat>DBT</assetCat>
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        <invCountry>US</invCountry>
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          <couponKind>Fixed</couponKind>
          <annualizedRt>4.00000000</annualizedRt>
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          <isCashCollateral>N</isCashCollateral>
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      <invstOrSec>
        <name>HAM LAKE MN CHRT SCH LEASE REV</name>
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          <isin value="US406511AC98"/>
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        <name>N TX TOLLWAY AUTH REVENUE</name>
        <lei>PQGZGRE0F2WPMYQQ1B78</lei>
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        <name>MECKLENBURG CNTY NC</name>
        <lei>5493006G3IC5PBHB7A65</lei>
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        <name>MISHAWAKA IN MF HSG REVENUE</name>
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          <isin value="US604786AB97"/>
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          <maturityDt>2038-01-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>5.37500000</annualizedRt>
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        <name>FLORIDA ST DEV FIN CORP SENIOR</name>
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          <maturityDt>2035-06-01</maturityDt>
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          <annualizedRt>5.00000000</annualizedRt>
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      <invstOrSec>
        <name>HOUSTON TX UTILITY SYS REVENUE</name>
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          <isin value="US44244CZZ30"/>
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        <name>UNIV OF VIRGINIA VA UNIV REVEN</name>
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        <name>PHILADELPHIA PA AUTH FOR INDL</name>
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        <name>MET PIER &amp; EXPOSITION AUTH IL</name>
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        <name>PUERTO RICO SALES TAX FING COR</name>
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      <invstOrSec>
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        <valUSD>1166600.00000000</valUSD>
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          <annualizedRt>5.00000000</annualizedRt>
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        <curCd>USD</curCd>
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        <name>MAINE ST TURNPIKE AUTH</name>
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        <title>Maine Turnpike Authority</title>
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          <isin value="US560551MJ92"/>
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        <curCd>USD</curCd>
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        <invCountry>US</invCountry>
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        <debtSec>
          <maturityDt>2042-07-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>5.00000000</annualizedRt>
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          <areIntrstPmntsInArrs>N</areIntrstPmntsInArrs>
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          <isCashCollateral>N</isCashCollateral>
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      <invstOrSec>
        <name>CALIFORNIA CNTY CA TOBACCO SEC</name>
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        <title>California County Tobacco Securitization Agency</title>
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        <identifiers>
          <isin value="US13016NFB55"/>
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        <balance>1000000.00000000</balance>
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        <curCd>USD</curCd>
        <valUSD>1211880.00000000</valUSD>
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        <assetCat>DBT</assetCat>
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        <invCountry>US</invCountry>
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        <debtSec>
          <maturityDt>2049-06-01</maturityDt>
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          <annualizedRt>5.00000000</annualizedRt>
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        <name>UNIV SYS OF MD AUXILIARY FAC &amp;</name>
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        <title>University System of Maryland</title>
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          <isin value="US91440AAX28"/>
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        <name>MET TRANSPRTN AUTH NY REVENUE</name>
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        <name>PENNSYLVANIA ST TURNPIKE COMMI</name>
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        <name>PWR CNTY ID INDL DEV CORP SOL</name>
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        <name>MET PIER &amp; EXPOSITION AUTH ILD</name>
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        <name>PUERTO RICO SALES TAX FING COR</name>
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        <name>MET PIER &amp; EXPOSITION AUTH IL</name>
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        <name>PUBLIC FIN AUTH WI EDUCTNL FAC</name>
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          <isin value="US74443DFJ54"/>
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        <name>CHARLESTON SC WTRWKS &amp; SWR REV</name>
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        <name>INDIANA ST FIN AUTH REVENUE</name>
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        <name>NEW YORK ST THRUWAY AUTH PERSO</name>
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        <name>BAY AREA CA TOLL AUTH TOLL BRI</name>
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        <name>PORTLAND ME ARPT REVENUE</name>
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          <isCashCollateral>N</isCashCollateral>
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        <name>EVANSVILLE IN MF HSG REVENUE</name>
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          <isCashCollateral>N</isCashCollateral>
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        <name>MIAMI-DADE CNTY FL WTR &amp; SWR R</name>
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        <curCd>USD</curCd>
        <valUSD>5532850.00000000</valUSD>
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        <name>OHIO ST HSG FIN AGY MF HSG REV</name>
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          <isin value="US676900UD33"/>
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        <valUSD>1004470.00000000</valUSD>
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        <name>NEW JERSEY ST ECON DEV AUTH SP</name>
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        <curCd>USD</curCd>
        <valUSD>2544650.00000000</valUSD>
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          <annualizedRt>5.75000000</annualizedRt>
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          <isCashCollateral>N</isCashCollateral>
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      <invstOrSec>
        <name>SEATTLE WA WTR SYS REVENUE</name>
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        <valUSD>4189681.30000000</valUSD>
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        <invCountry>US</invCountry>
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        <debtSec>
          <maturityDt>2032-08-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>4.00000000</annualizedRt>
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          <areIntrstPmntsInArrs>N</areIntrstPmntsInArrs>
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        <securityLending>
          <isCashCollateral>N</isCashCollateral>
          <isNonCashCollateral>N</isNonCashCollateral>
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        <name>MASSACHUSETTS ST DEV FIN AGY R</name>
        <lei>549300UZSVMFXJK08K70</lei>
        <title>Massachusetts Development Finance Agency</title>
        <cusip>57584XJB8</cusip>
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          <isin value="US57584XJB82"/>
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        <valUSD>1100480.00000000</valUSD>
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        <fairValLevel>2</fairValLevel>
        <debtSec>
          <maturityDt>2041-07-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>4.00000000</annualizedRt>
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          <isCashCollateral>N</isCashCollateral>
          <isNonCashCollateral>N</isNonCashCollateral>
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      <invstOrSec>
        <name>CALIFORNIA ST EDUCTNL FACS AUT</name>
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        <title>California Educational Facilities Authority</title>
        <cusip>130179GV0</cusip>
        <identifiers>
          <isin value="US130179GV07"/>
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        <balance>2000000.00000000</balance>
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        <curCd>USD</curCd>
        <valUSD>2847820.00000000</valUSD>
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        <debtSec>
          <maturityDt>2046-06-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>5.00000000</annualizedRt>
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          <areIntrstPmntsInArrs>N</areIntrstPmntsInArrs>
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      <invstOrSec>
        <name>BUCKEYE OH TOBACCO SETTLEMENT</name>
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        <title>Buckeye Tobacco Settlement Financing Authority</title>
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          <isin value="US118217CX40"/>
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        <valUSD>1080000.00000000</valUSD>
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        <invCountry>US</invCountry>
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          <maturityDt>2048-06-01</maturityDt>
          <couponKind>Fixed</couponKind>
          <annualizedRt>4.00000000</annualizedRt>
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        <securityLending>
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        <name>PENNSYLVANIA ST HSG FIN AGY SF</name>
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        <title>Pennsylvania Housing Finance Agency</title>
        <cusip>70879QKU6</cusip>
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          <isin value="US70879QKU66"/>
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        <balance>2000000.00000000</balance>
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        <curCd>USD</curCd>
        <valUSD>1832540.00000000</valUSD>
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          <couponKind>Fixed</couponKind>
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        <name>MARYLAND ST HLTH &amp; HGR EDUCTNL</name>
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        <title>Maryland Health &amp; Higher Educational Facilities Authority</title>
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        <issuerCat>MUN</issuerCat>
        <invCountry>US</invCountry>
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        <debtSec>
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          <couponKind>Fixed</couponKind>
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          <isCashCollateral>N</isCashCollateral>
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      </invstOrSec>
    </invstOrSecs>
    <signature>
      <ncom:dateSigned>2022-03-22</ncom:dateSigned>
      <ncom:nameOfApplicant>Pioneer Municipal High Income Fund, Inc</ncom:nameOfApplicant>
      <ncom:signature>Anthony J. Koenig, Jr</ncom:signature>
      <ncom:signerName>Anthony J. Koenig, Jr</ncom:signerName>
      <ncom:title>Managing Director, Chief Operations Officer &amp; Treasurer of the Funds</ncom:title>
    </signature>
  </formData>
  <documents>XXXX</documents>
</edgarSubmission>
