X0303 4 2011-02-08 0000066740 3M CO MMM 0001215821 BUCKLEY GEORGE W 3M CENTER ST. PAUL MN 55144-1000 1 1 CHAIRMAN OF THE BOARD & CEO Deferred Common Stock 2011-02-08 4 A 0 27648 0 A 27648 I By Corporation Non-qualified Stock Option (Right to Buy) 89.47 2011-02-08 4 A 0 213759 0 A 2012-02-08 2021-02-08 Common Stock 213759 213759 D This transaction reflects the delivery of 27,648 shares of 3M Common Stock earned as the result of the 2008 performance shares awarded to the reporting person under the 3M Performance Unit Plan. Of this total number of shares of Deferred Common Stock, the reporting person's former spouse has an economic benefit right to 5,100 shares of Deferred Common Stock (less taxes). The Deferred Common Stock becomes payable one year after the reporting person retires. The number of shares to be withheld for taxes is unknown. An amended filing will be done once the number of shares to be withheld for taxes is determined. This option becomes exercisable in equal installments on each of the first three anniversaries of the grant date (2/8/2011). George Ann Biros, attorney-in-fact for George W. Buckley 2011-02-10