<?xml version="1.0"?>
<ownershipDocument>

    <schemaVersion>X0206</schemaVersion>

    <documentType>3</documentType>

    <periodOfReport>2009-04-27</periodOfReport>

    <noSecuritiesOwned>1</noSecuritiesOwned>

    <issuer>
        <issuerCik>0001454978</issuerCik>
        <issuerName>Nuveen Pennsylvania Municipal Value Fund</issuerName>
        <issuerTradingSymbol>NPN</issuerTradingSymbol>
    </issuer>

    <reportingOwner>
        <reportingOwnerId>
            <rptOwnerCik>0001188721</rptOwnerCik>
            <rptOwnerName>AMBOIAN JOHN P</rptOwnerName>
        </reportingOwnerId>
        <reportingOwnerAddress>
            <rptOwnerStreet1>C/O NUVEEN INVESTMENTS</rptOwnerStreet1>
            <rptOwnerStreet2>333 W. WACKER DRIVE</rptOwnerStreet2>
            <rptOwnerCity>CHICAGO</rptOwnerCity>
            <rptOwnerState>IL</rptOwnerState>
            <rptOwnerZipCode>60606</rptOwnerZipCode>
            <rptOwnerStateDescription></rptOwnerStateDescription>
        </reportingOwnerAddress>
        <reportingOwnerRelationship>
            <isOther>1</isOther>
            <otherText>CEO of Investment Adviser</otherText>
        </reportingOwnerRelationship>
    </reportingOwner>

    <nonDerivativeTable></nonDerivativeTable>

    <derivativeTable></derivativeTable>

    <footnotes></footnotes>

    <remarks>amboianpoa.TXT
Due to an administrative error, prior filings for the reporting person with respect to the issuer were inadvertently omitted at the time the reporting person first became subject to the reporting requirements of Section 16 under the Securities and Exchange Act of 1934 with respect to the issuer.</remarks>

    <ownerSignature>
        <signatureName>Mark L. Winget/ Signed Under POA</signatureName>
        <signatureDate>2017-11-30</signatureDate>
    </ownerSignature>
</ownershipDocument>
