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Stockholders' Equity (Tables)
12 Months Ended
Dec. 31, 2018
Share-based Compensation Arrangement by Share-based Payment Award [Line Items]  
Schedule of warrants and options exercise prices and expiration dates
  Exercise
Price
  Number of
Shares
  Expiration
Date
 Warrants or
Options
  US$        
To non-employees            
             
   0.01   10,000  October 01, 2027 Options
   0.01   45,000  February 28, 2028 Options
   0.01   30,000  January 01, 2028 Options
   1.67   105,000  October 01, 2024 Options
   1.70   115,000  December 20, 2022 Options
   2.61   77,000  December 04, 2021 Options
To employees and directors            
             
   0.01   15,000  November 11, 2023 Options
   0.01   15,000  March 31, 2024 Options
   0.01   5,000  June 11, 2024 Options
   0.01   10,000  September 30, 2025 Options
   0.01   25,000  December 31, 2025 Options
   0.01   305,000  June 05, 2026 Options
   0.01   25,000  December 31, 2026 Options
   0.01   500,000  January 01, 2027 Options
   0.01   10,000  January 04, 2027 Options
   0.01   60,000  April 17, 2027 Options
   0.01   30,000  October 01, 2027 Options
   0.01   202,500  January 01, 2028 Options
   0.01   110,000  January 04, 2028 Options
   0.01   6,000  April 06, 2028 Options
   1.33   25,000  May 01, 2023 Options
   1.38   108,000  January 02, 2021 Options
   1.38   123,057  January 02, 2025 Options
   1.55   400,000  June 05, 2022 Options
   1.67   340,000  October 01, 2020 Options
   1.67   343,886  October 01, 2024 Options
   1.70   168,500  December 20, 2022 Options
   1.73   25,000  January 09, 2019 Options
   1.75   400,000  June 07, 2023 Options
   1.78   25,000  September 04, 2024 Options
   1.87   25,000  January 31, 2022 Options
   1.95   25,000  April 02, 2020 Options
   1.96   25,000  September 3, 2019 Options
   2.03   25,000  May 01, 2021 Options
   2.31   400,000  January 01, 2024 Options
   2.61   604,500  December 04, 2021 Options
   4.15   25,000  July 02, 2024 Options
To investors            
  1.00   243,853  May 02, 2020 Warrants
  1.00   546,050  October 29, 2020 Warrants
  1.00   

2,144,510

  March 03, 2020 Warrants
  1.00   359,610  August 14, 2020 Warrants
  1.00   240,578  January 08, 2021 Warrants
  2.00   1,498,804  January 31, 2020 Warrants
  3.00   640,735  June 29, 2020 Warrants
   5.00   372,400  April 19, 2020 Warrants
Total outstanding  1.56*  

10,834,983

     

   

* Weighted Average

Schedule of warrant and option transactions
  

Number of

shares

  

Weighted Average

exercise price

 
     US$ 
Outstanding, December 31, 2015  3,629,693   1.76 
         
Changes during 2016 to:        
Granted to employees, officers, directors and others  2,265,000   0.27 
Expired/Cancelled/Forfeited  (172,250)  2.76 
Exercised  (1,555,500)  0.01 
Outstanding, December 31, 2016  4,166,943   1.58 
         
Changes during 2017 to:        
Granted to employees, officers, directors and others  2,212,500   0.34 
Expired/Cancelled/Forfeited  (360,000)  2.32 
Exercised  (1,680,000)  0.33 
Outstanding, December 31, 2017  4,339,443   1.37 
         
Changes during 2018 to:        
Granted to employees, officers, directors and others*  

969,000

   1.11 
Expired/Cancelled/Forfeited  (237,500)  1.75 
Exercised  (282,500)  0.07 
Outstanding, December 31, 2018  4,788,443   1.37 
Exercisable, December 31, 2018  4,778,443   1.38 

 

*The receipt of a stock option grant by the grantee recipient is a non-taxable event according to the Internal Revenue Service. The grantee who later chooses to exercise penny stock options must recognize the market value in income in the year of exercise.
Schedule of stock warrants and options outstanding

 

Shares underlying outstanding options (non-vested)  Shares underlying outstanding options (fully vested) 
Range of
exercise
price
  Number outstanding  Weighted average remaining contractual life (years)  Weighted
Average
Exercise
price
  Range of exercise
price
  Number
Outstanding
  Weighted average remaining contractual life (years)  Weighted
Average
Exercise
price
 
US$        US$  US$        US$ 
        0.01  15,000      4.87  0.01 
             0.01   15,000   5.25   0.01 
             0.01   5,000   5.45   0.01 
             0.01   10,000   6.75   0.01 
             0.01   25,000   7.00   0.01 
             0.01   305,000   7.42   0.01 
             0.01   525,000   8.00   0.01 
             0.01   10,000   8.01   0.01 
             0.01   60,000   8.29   0.01 
 0.01   10,000   8.75   0.01   0.01   30,000   8.75   0.01 
             0.01   232,500   9.00   0.01 
             0.01   110,000   9.01   0.01 
             0.01   45,000   9.16   0.01 
             0.01   6,000   9.26   0.01 
             1.33   25,000   4.32   1.38 
             1.38   108,000   2.01   1.38 
             1.38   123,057   6.01   1.38 
             1.55   400,000   3.43   1.38 
             1.67   340,000   1.75   1.67 
             1.67   448,886   5.76   1.67 
             1.70   298,500   3.97   1.70 
             1.73   25,000   0.02   1.73 
             1.75   400,000   4.52   1.70 
             1.87   25,000   3.09   1.87 
             1.95   25,000   1.25   1.95 
             1.96   25,000   0.67   1.96 
             2.03   25,000   2.33   2.03 
             2.31   400,000   5.01   2.31 
                 2.61   681,500   2.93   2.61 
             4.15   25,000   5.51   4.15 
 0.01   10,000       0.01   0.01-4.15   4,778,443       1.38 
Schedule of warrants description

 

  Period of Grant US$  Expiration Date
        
ZNWAA Warrants March 2013 – December 2014  2.00  January 31, 2020
ZNWAD Warrants** January 2015 – March 2016  1.00  May 02, 2020
ZNWAE Warrants November 2016 – March 2017  1.00  May 01, 2020
ZNWAF Warrants** May 2017 – July 2017  1.00  August 14, 2020
ZNWAG Warrants October 2017 – December 2017  1.00  January 08, 2021
ZNWAH Warrants** February 2018  5.00  April 2, 2020
ZNWAI Warrants** April 2018 – May 2018  3.00  June 29, 2020
ZNWAJ Warrants August 2018 – September 2018  1.00  October 29, 2020
ZNWAK Warrants December 2018 – January 2019  0.01  February 25, 2020

 

*Zion’s ZNWAB Warrants expired on May 2, 2017 and its ZNWAC Warrants expired on May 2, 2018
**On December 4, 2018, the Company extended the termination date of the Warrants by one (1) year.
Dividend Reinvestment and Stock Purchase Plan [Member]  
Share-based Compensation Arrangement by Share-based Payment Award [Line Items]  
Schedule of warrants description

Change during 2016 to:

  

  ZNWAA  ZNWAB  ZNWAC  ZNWAD  ZNWAE  ZNWAF  ZNWAG  ZNWAH  ZNWAI  ZNWAJ  Total 
Outstanding warrants, December 31, 2015  1,567,155   287,072   287,072   287,072   -   -   -   -   -   -   2,428,371 
Exercise Price $2.00  $1.00  $1.00  $1.00  $1.00  $1.00  $1.00  $5.00  $3.00  $1.00     
Warrant Termination Date   1/31/2020   5/2/2017   5/2/2018   5/2/2020   5/2/2020   8/14/2020   1/8/2021   4/19/2020   6/29/2020    10/29/2020     
                                             
Change during 2016 to:                                      
                                             
Issued  -   95,180   95,180   95,180   803,376   -   -   -   -   -   1,088,916 
Exercised  -   (68,698)  (37,524)  (34,412)  -   -   -   -   -   -   (140,634)
Expired  -   -   -   -   -   -   -   -   -   -   - 
Outstanding and exercisable warrants, December 31, 2016  1,567,155   313,554   344,728   347,840   803,376   -   -   -   -   -   3,376,653 

 

Change during 2017 to:

 

   ZNWAA   ZNWAB   ZNWAC   ZNWAD   ZNWAE   ZNWAF   ZNWAG   ZNWAH   ZNWAI  ZNWAJ   Total 
Issued  -   -   -   -   3,262,742   683,865   414,300   -   -   -   4,360,907 
Exercised  (42,538)  (206,737)  (69,576)  (53,506)  (1,037,999)  (223,634)  -   -   -   -   (1,633,990)
Expired  -   (106,817)  -   -   -   -   -   -   -   -   (106,817)
Outstanding and exercisable warrants, December 31, 2017  1,524,617   -   275,152   294,334   3,028,119   460,231   414,300   -   -   -   5,996,753 

 

Change during 2018 to:

 

  ZNWAA  ZNWAB  ZNWAC  ZNWAD  ZNWAE  ZNWAF  ZNWAG  ZNWAH  ZNWAI  ZNWAJ  Total 
Issued  -   -   -   -   10,493   100   6,030   373,900   656,274   550,900   

1,597,697

 
Exercised  (25,813)  -   (196,913)  (50,481)  (894,102)  (100,721)  (179,752)  (1,500)  (15,539)  (4,850)  (1,469,671)
Expired  -   -   (78,239)  -   -   -   -   -   -   -   (78,239)
Outstanding and exercisable warrants, December 31, 2018  1,498,804   -   -   243,853   

2,144,510

   

359,610

   240,578   372,400   640,735   546,050   

6,046,540

 
Non Employees [Member]  
Share-based Compensation Arrangement by Share-based Payment Award [Line Items]  
Schedule of assumptions used to estimate fair value of warrants granted using black-scholes option pricing model

  For the year ended 
December 31,
 
  2018  2017  2016 
Weighted-average fair value of underlying stock at grant date $3.37  $1.56  $1.51 
Dividend yields         
Expected volatility  73%-76%   68%-72%   69%-70% 
Risk-free interest rates  2.46%-2.81%   2.36%-2.44%   1.73%-1.83% 
Expected lives (in years)  10.00   10.00   10.00 
Weighted-average grant date fair value $3.36  $1.55  $1.50
Non Employees [Member] | Warrants and Options [Member]  
Share-based Compensation Arrangement by Share-based Payment Award [Line Items]  
Schedule of compensation cost of warrant and option issuances

 

For the year ended December 31, 
2018  2017  2016 
US$  US$  US$ 
 302,000   276,000   360,000 
Employees and Directors [Member] | Warrants and Options [Member]  
Share-based Compensation Arrangement by Share-based Payment Award [Line Items]  
Schedule of compensation cost of warrant and option issuances

 

For the year ended December 31, 
2018  2017  2016 
US$  US$  US$ 
 1,553,000   2,448,000   2,726,000 
Employees [Member]  
Share-based Compensation Arrangement by Share-based Payment Award [Line Items]  
Schedule of assumptions used to estimate fair value of warrants granted using black-scholes option pricing model

 

  For the year ended
December 31,
 
  2018  2017  2016 
Weighted-average fair value of underlying stock at grant date $2.38  $1.48  $1.56 
Dividend yields         
Expected volatility  68%-87%  45%-69%  57%-69% 
Risk-free interest rates  2.01%-2.74%  1.45%-1.94%  0.94%-1.93% 
Expected lives (in years)  3.00-5.50   3.00-5.87   3.00-5.50 
Weighted-average grant date fair value $1.72  $1.23  $1.35 
Employees [Member] | Warrants and Options [Member]  
Share-based Compensation Arrangement by Share-based Payment Award [Line Items]  
Schedule of compensation cost of warrant and option issuances
For the year ended December 31, 
2018  2017  2016 
US$  US$  US$ 
 348,000   256,000   213,000